Welcome to the third instalment of Grease 101. In PART 1 of the series, we provided an overview of grease lubricants, covering aspects like base penetrability, NLGI grade classification, grease drop-point, and dmN factor measurement. In PART 2, we explored lubricating oil and thickeners, elucidating their types and inter-compatibility. This third and final part of the series is dedicated to additives, the third grease lubricant component. We’ll delve into their various types, assess advantages and constraints, and conclude with a rundown of greasing techniques.
Also read:
Types of Lubrication: Boundary vs Hydrodynamic Lubrication
What Are Release Agents? What Are Its Types?
Static and Dynamic Systems: Differences and Information
Additives Definition
Additives are components added to lubricating oils to enhance their performance, particularly in boundary lubrication situations where two Surfaces are in direct contact. These additives can exist in either liquid or solid forms.
Liquid Additives
Anti-wear Agents
Anti-wear agents are additives that serve to prevent the wear and tear of surfaces that are in motion. These agents form a protective layer on the surface, minimising friction and reducing the likelihood of damage due to mechanical contact between moving parts. By creating a barrier between the surfaces, they help extend the lifespan of the lubricated components.
Anti Oxidizing Agents
In high-temperature conditions, lubricating oils can experience oxidative degradation, leading to reduced performance and the formation of harmful byproducts. Anti-oxidising agents are added to the oil to counteract these effects. They work by inhibiting the chemical reactions that cause oil to break down under high temperatures, extending the oil’s usable life and maintaining its effectiveness.
Anti-Rust Agents
Lubricated components are often exposed to environmental factors like water and humidity, which can lead to corrosion and rust formation. Anti-rust agents are incorporated into the lubricating oil to enhance its resistance against these factors. These additives form a protective barrier on metal surfaces, preventing moisture penetration and inhibiting the formation of rust, which helps maintain the integrity of the components.
Extreme Pressure Agents (EP)
When lubricated surfaces are subjected to high loads or extreme pressures, the lubricating film can be squeezed out, resulting in direct metal-to-metal contact. Extreme pressure agents are included in the oil to address this issue. They chemically react with the metal surfaces under high pressure, forming a protective layer that prevents welding and galling of the surfaces. This ensures that the lubricating film remains intact even under heavy loads, reducing friction and wear.
Adhesion Agents (Synthorium)
Adhesion agents are specialised additives that enhance the oil’s ability to adhere to surfaces. Synthorium is an adhesion agent that improves the oil’s affinity to stick to surfaces, even under demanding conditions. This is particularly useful when the lubricating film could be displaced due to movement or vibration. By promoting stronger adhesion, these agents ensure the lubricating film remains in place, maintaining a consistent barrier between moving parts.
Solid Additives
Solid additives enhance the efficacy of grease lubricant in extreme conditions where base oil alone may not suffice due to high temperatures, extreme temperatures, pressures, or other challenging environments. Additionally, in situations where the base oil’s viscosity might break down or fail to adequately separate moving surfaces, solid additives provide an additional layer of protection.
Graphite
Over 99% Carbon
Graphite is composed primarily of carbon atoms arranged in a hexagonal lattice structure.
Lamellar Hexagonal Structure
Graphite’s structure consists of closely packed layers of carbon atoms arranged in a hexagonal pattern. These weakly bonded layers can easily slide over one another, giving graphite its lubricating properties.
Good Dry Lubricant
The layered structure allows individual sheets to slide smoothly, reducing surface friction.
Excellent Resistance to High Temperatures (900°C)
Graphite exhibits exceptional thermal stability. It can withstand high temperatures without undergoing significant chemical changes or degradation.
Good Electrical Properties
Due to its high electrical conductivity, graphite is often used in applications requiring electrical conductivity, such as in electrical brushes, contacts, and certain industrial processes.
Good Thermal Conductivity
Graphite also possesses good thermal conductivity, allowing it to dissipate heat effectively. This property makes it suitable for use in applications where heat needs to be managed, such as in heat sinks or thermal management systems.
Good Anti-Corrosion Properties
Graphite’s layered structure and chemical inertness contribute to its anti-corrosion properties. It can act as a barrier, protecting surfaces from corrosive elements and preventing direct contact between metals that might lead to galvanic corrosion.
Moderate Adhesion to Surfaces
Graphite exhibits moderate adhesion to surfaces. While it doesn’t firmly adhere like some other materials, its slight adhesion can be beneficial in helping the graphite particles to stick to the surfaces they need to lubricate.
Molybdenum Disulphide (MoS2)
Found in Granite Veins and Highly Refined
Molybdenum Disulfide (MoS2) is a mineral found in granite veins and other geological formations. It’s often refined and processed for industrial applications to achieve specific purity levels and particle sizes suitable for various uses.
Lamellar Hexagonal Structure with Easy Shear Property
Similar to graphite, MoS2 has a layered, hexagonal lattice structure. This structure allows the individual layers to easily shear or slide over one another, which gives MoS2 its exceptional lubricating properties.
Excellent Dry Lubricant
Its lamellar structure enables it to create a boundary layer between surfaces, reducing friction and wear even in the absence of traditional liquid lubricants.
High Extreme Pressure (EP) Performance
MoS2 excels in extreme pressure conditions where metal surfaces are subjected to heavy loads and pressures. It forms a protective layer that prevents direct metal-to-metal contact and helps prevent wear, galling and other surface damages.
Excellent Adhesion to Surfaces
MoS2 exhibits strong adhesion to metal surfaces, which enhances its ability to stay in place and provide consistent lubrication even under demanding conditions.
Non-Conductive
This property is beneficial in applications where electrical conductivity must be avoided or minimised.
Corrodes Metals at High Temperatures (450°C)
One limitation of MoS2 is that it can promote corrosion in certain metals at high temperatures, around 450°C and above. This corrosion occurs due to the MoS2 particles’ interaction with the metal surface under specific conditions.
Poly Tetra Fluoro Ethylene (PTFE)
Excellent Friction Coefficient due to Low Surface Energy
PTFE is known for its remarkable lubricating properties, primarily attributed to its deficient surface energy. This property results in an exceptionally low friction coefficient, often as low as 0.04 or even lower, making it an ideal choice for reducing friction and wear between surfaces.
Not Layered Structure
Unlike graphite and molybdenum disulfide, PTFE does not have a layered structure. Instead, it consists of long, linear molecules with strong carbon-fluorine bonds. This unique structure contributes to its self-lubricating properties.
Macromolecules Slip Easily Along Each Other
The long-chain molecules in PTFE are slippery, allowing them to slide past each other with minimal resistance.
White Color
PTFE is naturally white in colour, which can be advantageous in applications where the appearance of the lubricated components is important.
Food Grade
PTFE is approved for use in food-related applications due to its non-toxic and non-reactive nature. It is often used in food processing and packaging machinery.
Operating Temperature Limited to 260°C
While PTFE offers excellent lubricating properties, its operating temperature is limited to around 260°C (500°F). Beyond this temperature, PTFE can begin to degrade, potentially affecting its performance and introducing other considerations like outgassing.
Metallic Salts
Lubrication
Certain Metallic Salts possess inherent lubricating qualities, helping to reduce friction and wear between surfaces. This can be particularly beneficial in applications where solid lubrication is preferred over liquid lubricants.
Adhesion to Surfaces
Metallic salts can enhance the adhesion of the grease lubricant to surfaces, ensuring that the lubricant remains in place even under challenging conditions. This improved adhesion contributes to longer-lasting lubrication and protection.
Conductivity
Some metallic salts, like certain compounds of zinc and selenium, can offer electrical conductivity. This can be advantageous in applications where maintaining electrical contact or grounding is necessary.
Limited Usage
While metallic salts can provide valuable properties to grease lubricant formulations, they are not as commonly used as other solid additives like graphite or molybdenum disulfide. The selection and use of metallic salts as additives depend on the specific lubrication requirements and the salts’ compatibility with the other grease components.
