World-record signing Neymar missed Saturday's 0-0 away draw against Montpellier in Ligue 1 due to a foot injury, the first game Unai Emery's men have failed to win this season.
Di Maria has not played for PSG since August after suffering a thigh injury on international duty, but is now set for a comeback after a four-game absence.
Emery confirmed he will be able to call upon both Neymar and Di Maria for the match against their biggest rivals to win Group B at the Parc des Princes.
Both Bayern Munich and PSG won their opening Champions League fixtures and sit at three points on top of the group.
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